MadSci Network: Science History |
Why is the periodic table so uniquely shaped? Dear scientist, I was wondering if you could help me to understand why the periodic table has such a unique shape, and what is that suppose to tell us about atoms? Any information you could pass along would be appreciated, thanks. Sincerely, Carrie Dear Carrie, The periodic table need not have any particular shape as long as it properly represents what it is supposed to represent: the chemical properties of the elements. Elements on the periodic table were initially grouped according to the ratio of the element to the oxygen in the element's oxide. For example, elements such as lithium and potassium, which form oxides according to E2O, were in one group; elements which form oxides according to EO (such as copper, zinc, calcium) were in another group; elements which form oxides E2O3 (boron, aluminum, iron) in yet another; and so forth. Before long we realized that not everything is the same. For example, iron forms two different oxides: FeO and Fe2O3; while carbon only forms one oxide, CO2. But subtle distinctions aside, the elements were grouped according to their chemical properties -- and they still are. Now the table has a slightly different organizing principle (electronic structure and atomic number) but since chemical properties follow this closely, the table is still grouped according to chemical properties. The essential design elements (though it wasn't humans who designed it! they are dictated by chemical and physical properties!) in the periodic table are as follows:
But as long as the table preserves the design constraints listed above (which keep elements in groupings by chemical properties), it can have any sort of shape. Some alternative versions (not all of them holding to the design elements chemists think are important) are found here.
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