MadSci Network: Chemistry |
Hi, at first great project (!!!) and thank you very much for doing this! I'm asking because I'm trying to understand a chemical reaction I've observed in my kitchen, when trying to make sugar-based crash-glass. The basic experiment: destilled water, sucrose and either citric or tartaric acid are heated in a pot up to around 140°C/284°F, just before it caramelizes. I know the following from previous research and experimenting: - The acid splits the sucrose into glucose and fructose, which act as interferring agents (as do the 2 acids themselves, hydrogen bridges...) and prevent crystallisation. - The mass is less hygroscopic than without the acid. - The mass already turns slightly yellowish (with tartaric acid less than with citric acid) just before reaching the caramelizing-temperature. It doesn't happen without an acid or with vinegar. - When cooling down the mass takes longer to cure than without the acid (much more suited for shaping). My theories with regard to the last three points: - The structures of sucrose and citric/tartaric acid fit together very good (less free OH-groups attracting water). - Maybe an ester is formed. The 2/3 carboxyl-groups hold the possibility of building polymers causing the color -> delocalisation. Maybe the acid just reacts with itself (just heat the acid and it also turns yellow). - Also hydrogen bridges, but I don’t really have a concrete idea. Can you explain what causes my observations (last three points)? Is an ester formed?
Re: What happens when mixing sucrose and tartaric/citric acid?
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