MadSci Network: Chemistry |
I can see from the way that you ask your question that you have been told a number of things that are really simplified ways of looking at things that are not quite true. So I think it is best if we make a complete new start. Although it is true that silver, gold, and platinum are very unreactive metals, it is not true that they do not form ions. Silver is present as Ag+ in a silver nitrate solution in water. Gold ions in solution do not normally occur, but solutions can be prepared which contain these ions. An ion forms when an atom loses one or more electrons to leave it with an excess of positive charge. Negative ions can also form if an atom picks up extra electrons. There is nothing special about gold or silver or platinum in this: like all other elements they can lose electrons to form an ion. Different atoms hold onto their electrons more or less strongly. It takes more energy to remove an electron from some atoms than others. Gold is one of the harder elements to remove an electron from. But it is not the hardest, even among metals. Zinc, which you will know is quite a reactive metal, is harder to remove an electron from than gold! But nearly all of the chemistry we are thinking about when we are talking about ions is the chemistry of aqueous solutions and of ionic crystals. The presence of water, or of a crystal lattice, stabilizes ions, and makes them more favourable. This is especially the case for smaller ions, and for multiply charged ions. The ions of silver and gold are relatively large, and only have a single charge, so they do not get as much benefit from this water stabilization or crystal field stabilization. Zinc ions are smaller, and doubly charged, so they are much easier to make in aqueous solutions or salt crystals than silver or gold ions. Finally, a word about what you have said about full outer electron shells. This idea works very well for light elements, but it gets a bit blurred for the heavier elements. That is why the periodic table gets sort of complicated and harder to use with heavier elements. As well as electron shells, there are subshells, designated s, p, d, and f. When you get to heavier elements, some of the d and f subshells have much the same energy as the s and p subshells of the next shell up. This makes a real difference to the sorts of ions that form. For example: light elements O(2-), F-, Na+, Mg(2+), and Al(3+), the common ionic forms of each of these elements all have the same configuration as Ne with a filled outer shell: 1s2 2s2 2p6 but with heavier elements Cr(2+) 1s2 2s2 2p6 3s2 3p6 3d4 Mn(2+) 1s2 2s2 2p6 3s2 3p6 3d5 Fe(2+) 1s2 2s2 2p6 3s2 3p6 3d6 Co(2+) 1s2 2s2 2p6 3s2 3p6 3d7 Ni(2+) 1s2 2s2 2p6 3s2 3p6 3d8 Cu(2+) 1s2 2s2 2p6 3s2 3p6 3d9 Zn(2+) 1s2 2s2 2p6 3s2 3p6 3d10 are all common ionic forms of the respective elements, but only zinc has a filled outer shell.
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