MadSci Network: Chemistry |
Dear Michele; For the iron to rust "Oxidize" there must be both water and oxygen present. In pure water with no air present, iron reacts with water only very slowly. In dry air, it also rusts very slowly. In the California desert, I have seen tin cans still shiny after several years exposure. The presence of salt in the water would speed up the reactions of air and water with the iron since the salt water will conduct electricity much better than plain tap water. Since the oxidation of iron [in fact,nearly all corrosion] is an electrochemical reaction this would aid in the passage of electrons. But, where the iron is covered with water, the access to air is minimized, so rusting is slow. You may have observed that the rusting appeared mostly at or just below the water level. Repeat this test with the steel wool only partly submerged in the salt water, it may rust faster. I am forwarding to you directly via eMail a response I made to a similar query a few weeks ago. I hope it will answer some of your questions. Charlie Crutchfield
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