MadSci Network: Physics |
The energies E of the hydrogen levels are given in electron volts (eV) by the formula E=-13.6 / n^2, where n^2 means n squared, and n is any non-zero positive integer: 1, 2, 3, 4, ... As you see, there is an infinite number of levels, yet they are all within the interval -13.6 eV to 0 eV. The electron can be excited to any of these levels, in a single jump or several jumps through intermediate levels. The electron can also be excited to a positive energy to become free from the atom if it absorbs enough energy. This is called "ionization". Thus if the electron is in the lowest state: n=1 (E=-13.6 eV), and it receives an energy greater than 13.6 eV, the atom will be ionized. Of course if the electron is in state, say, n=5, we need at least 13.6/25=0.54 eV to ionize the atom. The energy needed to set an electron free from the atom is called the binding energy. The above applies to an isolated atom. The radius of the orbit of an electron in state n in amstrongs is 0.529 n^2 Since n can be arbitrarily large, the orbit can be as large as we want, and this is unrealistic because atoms are usually surrounded by other atoms or particles that are colliding with it all the time. As n grows, the binding energy of the electron becomes weaker. At some point those collisions with its surroundings will give the electron enough energy to overcome its binding energy and ionize the atom. This means that no atom can really have an infinite number of levels. The number of effective levels that an atom has depends on how far other atoms are, that is, it depends on the density of the medium. In interstellar space, atoms can have several hundred levels, while in the atmosphere atoms only have a few n states.
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