MadSci Network: Physics
Query:

Re: why glass conducts electricity when it is hot , not when it is cold.

Date: Sat Apr 14 11:01:19 2007
Posted By: James Griepenburg, , Chemical consultant, Chemmet Services
Area of science: Physics
ID: 1175631867.Ph
Message:

Walter,

Most glasses are a solid solution of silicates and metal oxides
 http://glassproperties.com/glasses/

Glasses are usually ionic solids, however, the ions are immobilized and 
cannot conduct electricity by ionic conduction.
 http://en.wikipedia.org/wiki/Electrical_conduction

Electrical conduction requires that charged particles be able to move 
thru the material. [It also requires a source of electrons and an anode 
and cathode reaction for ionic conduction]  These particles are usually 
electrons in conductors such as metals or semiconductors.  Solid state 
ionic compounds such as common salt, NaCl, or glass are usually 
insulators until either the ions are dissolved in a solvent such as salt 
water or molten as in melted salts or molten glass, or, if the material 
has semiconductor properties, a higher temperature increases  electrons 
in a conduction band and therefore increases conduction.  Pure salts 
usually have a sharp melting point with a rather abrupt increase in 
conductivity.  Glasses, being a mixture and almost a very viscous liquid, 
will show a more gradual increase in conductivity.  Finally if the 
applied voltage is high enough to cause dielectric breakdown any material 
will become a conductor.

Descriptions of simple ionic conduction can be found in most general 
science texts or basic chemistry texts.  A local high school science 
teacher might be willing to give some demonstrations to your classes.

Regards,
JimG



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